Limonite
Limonite
Limonite is an iron ore mineral widely recognised for its yellow-brown colour and its frequent association with other iron-rich minerals. Unlike some other minerals, limonite is not a specific mineral but a mixture of hydrated iron oxide minerals, predominantly goethite and hematite, along with various impurities. Limonite is primarily used in the production of iron and steel and as a pigment due to its unique coloration. It is also used as an aggregate in high-density concrete and other specialised applications.
Chemical Composition and Properties
– General Formula: FeO(OH) · nH₂O (where “n” represents the varying amount of water in its structure)
– Primary Components: Iron(III) oxide-hydroxide with varying levels of hydration
– Iron Content: Typically around 50% to 66% iron by weight
– Colour: Ranges from yellow to brown to black, depending on impurities and weathering
– Crystal System: Amorphous to earthy or cryptocrystalline (not typically in well-defined crystals)
– Hardness: 4 – 5.5 on the Mohs scale
– Specific Gravity: 2.7 – 4.3
Chemical Information
– CAS Number: 1317-63-1 (for hydrated iron oxide, commonly used to refer to limonite as well)
– Chemical Composition: A mix of iron oxides, hydroxides, and water molecules in variable amounts, commonly represented by FeO(OH) · nH₂O.
– Molecular Weight: Variable, due to the fluctuating hydration state
– HS Code: 2601.20.00.00 (for iron ores and concentrates, other than roasted iron pyrites)
Formation and Occurrence
Limonite is often formed in the oxidation zones of iron-rich deposits. It can also occur as a secondary mineral from the weathering of iron-bearing rocks and minerals such as pyrite, magnetite, and hematite. It is commonly found in sedimentary environments and bogs, where it accumulates in large deposits as “bog iron ore.”
Specifications
Typical Properties
Iron(III) oxide - Fe2O3 | 75% |
Chlorine - Cl | 1.03% |
Silicon dioxide - SiO2 | 7.50% |
Manganese(II) oxide - MnO | 0.25% |
Barium oxide - BaO | 0.45% |
Aluminium oxide - AL2O3 | 1.25% |
Zinc oxide - ZnO | 0.05% |
Sodium oxide - Na2O | 0.65% |
Potassium oxide - K2O | 0.19% |
Calcium oxide - CaO | 0.69% |
Magnesium oxide - MgO | 0.34% |
Phosphorus Pentoxide - P2O5 | 0.48% |
Titanium dioxide - TiO2 | 0.18% |
Sulphur trioxide - SO3 | 0.90% |
Loss On Ignition | 10.20% |
Sizing | 0-40 mm or 0-10mm |